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// -*- mode: C++; tab-width: 4; indent-tabs-mode: nil; c-basic-offset: 4 -*- |
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// vi: set et ts=4 sw=4 sts=4: |
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// |
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// SPDX-FileCopyrightInfo: Copyright © DuMux Project contributors, see AUTHORS.md in root folder |
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// SPDX-License-Identifier: GPL-3.0-or-later |
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// |
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/*! |
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* \file |
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* \ingroup Binarycoefficients |
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* \brief Binary coefficients for water and heavy oil. |
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*/ |
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#ifndef DUMUX_BINARY_COEFF_H2O_HEAVYOIL_HH |
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#define DUMUX_BINARY_COEFF_H2O_HEAVYOIL_HH |
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#include <dumux/material/components/h2o.hh> |
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#include <dumux/material/components/heavyoil.hh> |
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namespace Dumux { |
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namespace BinaryCoeff { |
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/*! |
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* \ingroup Binarycoefficients |
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* \brief Binary coefficients for water and heavy oil as in SAGD processes |
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*/ |
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class H2O_HeavyOil |
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{ |
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public: |
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/*! |
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* \brief Henry coefficient \f$[N/m^2]\f$ for heavy oil in liquid water. |
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* \param temperature the temperature \f$\mathrm{[K]}\f$ |
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* |
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* \todo values copied from TCE, please improve it |
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*/ |
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template <class Scalar> |
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static Scalar henryOilInWater(Scalar temperature) |
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{ |
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// values copied from TCE, TODO: improve this!! |
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Scalar dumuxH = 1.5e-1 / 101.325; // unit [(mol/m^3)/Pa] |
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dumuxH *= 18.02e-6; //multiplied by molar volume of reference phase = water |
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return 1.0/dumuxH; // [Pa] |
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} |
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/*! |
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* \brief Henry coefficient \f$[N/m^2]\f$ for water in liquid heavy oil. |
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* \param temperature the temperature \f$\mathrm{[K]}\f$ |
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* |
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* \todo arbitrary value, please improve it |
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*/ |
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template <class Scalar> |
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static Scalar henryWaterInOil(Scalar temperature) |
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{ |
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// arbitrary, TODO: improve it!! |
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return 1.0e8; // [Pa] |
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} |
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/*! |
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* \brief Binary diffusion coefficient [m^2/s] for molecular water and heavy oil. |
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* \param temperature the temperature \f$\mathrm{[K]}\f$ |
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* \param pressure the phase pressure \f$\mathrm{[Pa]}\f$ |
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* |
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* \todo value is just an order of magnitude, please improve it |
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*/ |
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template <class Scalar> |
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static Scalar gasDiffCoeff(Scalar temperature, Scalar pressure) |
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{ |
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return 1e-6; // [m^2/s] TODO: This is just an order of magnitude. Please improve it! |
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} |
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/*! |
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* \brief Diffusion coefficient [m^2/s] for heavy oil in liquid water. |
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* \param temperature the temperature \f$\mathrm{[K]}\f$ |
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* \param pressure the phase pressure \f$\mathrm{[Pa]}\f$ |
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* |
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* \todo value is just an order of magnitude, please improve it |
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*/ |
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template <class Scalar> |
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static Scalar liquidDiffCoeff(Scalar temperature, Scalar pressure) |
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{ |
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return 1.e-9; // This is just an order of magnitude. Please improve it! |
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} |
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}; |
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} // end namespace BinaryCoeff |
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} // end namespace Dumux |
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#endif |
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